Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag     

NING Chuanxiang  MA Zhongliang  JIANG Zhenxue  SU Siyuan  LI Tingwei  ZHENG Lunju  WANG Guozhen  LI Fengxun 《《地质学报》英文版》2020,94(2):352-363

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.  相似文献   

利用偏光显微镜反射光系统观察黑色生油岩电子探针薄片中的生烃母质特征     

郑庆华  刘行军  刘乔  梁秀玲  张小龙  左琴  杨开艳  马婷  许锋 《岩矿测试》2020,39(3):442-450

鄂尔多斯盆地上三叠统延长组长7油层组的黑色泥岩、油页岩等黑色生油岩薄片中的生烃母质,因黑色石油、沥青等黑色有机质的覆盖或不透明,导致其在偏光显微镜透射光系统下观察常局部或整体呈现为黑色。因此,建立一种黑色生油岩薄片中生烃母质有效观察的方法,对致密油、页岩油的生烃研究具有重要的理论和实际意义。本文提出了一种利用电子探针薄片和偏光显微镜的反射光系统观察黑色生油岩中生烃母质特征的方法。该方法能够克服黑色生油岩薄片中生烃母质因被黑色有机质覆盖或不透明,而在偏光显微镜的透射光系统下局部或整体呈黑色的弊端,能够对生烃母质的大小、形态、结构、分布和物质成分等特征进行整体且清晰的观察。实践表明,本文提出的利用偏光显微镜反射光系统观察黑色生油岩电子探针薄片中生烃母质特征的方法,简单有效,易在致密油、页岩油的生烃研究领域推广使用。  相似文献   

云南哀牢山-红河剪切带新生代富碱侵入岩中榍石年代学和地球化学特征     

马倩  杨岳衡  赵志丹  佟鑫  武精凯  苗壮  李晨  雷杭山 《岩石学报》2020,36(9):2751-2764

榍石作为副矿物在哀牢山-红河剪切带新生代富碱侵入岩中广泛存在。原位获取榍石矿物内部微量元素、U-Pb年龄和Sm-Nd同位素的空间变化对获取矿物和岩石的成因演化信息具有重要意义。本文使用四级杆/多接收电感耦合等离子体质谱(Quadrupole/Multi-Collector Inductively Coupled Plasma Mass Spectrometry,Q/MC-ICP-MS)与激光剥蚀系统(Laser Ablation,LA)联用,对哀牢山-红河剪切带5个富碱侵入岩体(桃花岩体、宁蒗-永胜岩体、哈播岩体、铜厂岩体和十里村岩体)中榍石开展了微区原位微量元素、U-Pb年代学和Sm-Nd同位素研究。微量元素分析结果表明,三江富碱侵入岩中榍石为岩浆成因,亏损Rb、Ba、Pb、Sr等大离子亲石元素,富集Th、U、Nb、Ta、Zr、Hf等高场强元素。榍石的稀土配分图均表现为明显右倾,不具有或具有弱的Eu负异常。与云南北衙、马厂箐矽卡岩矿床中的热液榍石相比,本文榍石在稀土元素组成上,具有较高的稀土元素总量、较高的Th/U、LREE/HREE和Ce/Ce*比值,具有较低的Eu/Eu*、Nb/Ta、Zr/Hf比值。微区原位LA-Q-ICP-MS U-Pb定年结果表明,研究区富碱岩体中榍石结晶年龄在32.5～37.9Ma之间,代表了岩体形成时代,与三江地区哀牢山-红河剪切带及其附近新生代富碱岩浆活动高峰期(～35Ma)一致,属于青藏高原晚碰撞期岩浆作用的产物。榍石微区原位LA-MCICP-MS Sm-Nd同位素分析结果显示,榍石颗粒的Nd同位素组成均一,表明榍石结晶过程中寄主岩浆的Nd同位素组成没有发生明显变化。各个富碱岩体之间的榍石Nd同位素组成变化范围在-6.8～-2.1之间,与全岩的同位素特征一致,表明榍石的原位微区Sm-Nd同位素可以作为富碱侵入岩研究中有效的示踪手段之一。  相似文献   

四川甲基卡锂矿伟晶岩转石分布区“3定2参”大比例尺填图法及其在青藏高原应用的意义   总被引：4，自引：0，他引：4  

刘善宝  王成辉  王登红  代鸿章  马圣钞  于扬  潘蒙  郝雪峰  杨荣 《地质学报》2020,94(1):326-332

我国西部地区无论是新疆阿尔泰还是地处青藏高原的西昆仑地区或是松潘-甘孜成矿带,都是我国伟晶岩型矿床找矿远景区,但要么剥蚀严重,要么第四系覆盖,难以找到好的地质露头。本文以地处青藏高原东南缘的川西甲基卡矿田为例,通过近10年来的实践,探索出一套在第四系覆盖严重但又有伟晶岩转石分布地区的填图找矿方法--"3定2参"1∶2000伟晶岩转石填图法,即:定伟晶岩转石类型、尺度、密度,参考矿区内伟晶岩脉产状和地形条件。实践证明,该方法能够快速有效识别伟晶岩转石类型(冰碛物、坡积物和原地或半原地型),并可进一步确定第四系覆盖区内伟晶岩脉的类型、产状及规模,为钻探工程部署提供依据。2019年在甲基卡经8个钻孔验证,在日西柯第四系覆盖区内发现16条花岗伟晶岩脉,其中锂辉石伟晶岩脉10条,实现了新的找矿突破。这一方法同样在可尔因矿集区适用,并指导2019年"松潘-甘孜成锂带锂铍多金属大型资源基地综合调查评价"项目在上述两个地区实施钻探验证,初步探获新增氧化锂资源量超过15万吨,值得进一步推广应用。  相似文献   

黄土河谷场地地形放大效应的研究     

王良  卢育霞  马林伟  孔德政 《大地测量与地球动力学》2018,38(2):167-171

使用黄土河谷场地模型对地震动峰值加速度和频谱特征进行研究。结果表明，不同工况下各观测点PGA的放大比呈现出不同的变化规律。分析山顶和山谷各点的傅里叶谱以及谱比发现，在地形和土层共同作用下的放大效应是各自单独作用下放大效应的乘积。  相似文献   

渤海海峡跨海通道建设对城市经济联系的影响分析          下载免费PDF全文

狄乾斌  马洁 《海洋开发与管理》2018,35(3):102-108

渤海海峡跨海通道建设将极大改变环渤海乃至整个东部沿海的交通格局,势必对其目标城市大连、烟台带来直接的经济影响,同时也会对辽东半岛、山东半岛乃至东北、华北和华东不同尺度地区的经济联系产生深远影响。文章选取山东省17个和辽宁省14个地级市的地区的生产总值、城市人口以及城市间的最短时间距离等指标,测度渤海海峡跨海通道建成前后,对山东、辽宁两省区域城市经济联系的影响。研究表明:渤海海峡跨海通道建成后,对大连、烟台间的经济联系强度有显著提高,各城市经济联系度的平均增幅明显不同;同时,受距离衰减规律的影响,两省的城市分别以大连、烟台为中心,根据距离远近及城市自身发展程度分为4个层次,经济联系强度由内向外逐层次减弱;从整体上看,渤海通道的建设对带动两省城市之间的经济联系度都有大幅度提升。  相似文献   

Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N   总被引：1，自引：0，他引：1  

荣坤波  曾志刚  殷学博  陈帅  王晓媛  齐海燕  马瑶 《海洋学报(英文版)》2018,37(9):67-81

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.  相似文献   

对山东省绿色矿山建设与发展的思考          下载免费PDF全文

陈国栋  郭宝奎  刘瑄  张超  密娜 《山东国土资源》2018,34(6)

绿色矿山建设是矿业健康持续发展的时代要求,是矿产资源管理制度改革发展的重要方向,是建设生态文明、矿业转型升级的必然选择,是山东省矿业发展的必由之路。该文重点论述绿色矿山的内涵、基本条件、重要意义,分析了山东省绿色矿山建设面临的数量偏少、地方标准不健全、各职能部门协同机制有待进一步完善等多方面问题。并在此基础上,提出下步山东省绿色矿山建设的几点建议,包括严格规划管控、坚持试点引路及推进标杆企业建设、加快标准制定及出台相关管理办法、积极推动绿色矿业发展示范区建设等多项建议。  相似文献   

济南东部岩溶水有机污染健康风险评价          下载免费PDF全文

张海林  林广奇  马河宽  刘文 《山东国土资源》2018,34(11)

近年来,济南岩溶水有机污染越来越突出,为了探究济南岩溶水有机污染对居民健康造成的影响,保障饮用水安全,该文在系统分析研究区水文地质条件的基础上,采用USEPA推荐的健康风险评价模型,根据实际采样测试数据,分析评价了济南东部3处岩溶水井点的有机污染对其范围内暴露人群造成的健康风险。结果表明:检出的主要有机污染物为三氯甲烷、四氯化碳、三氯乙烯、四氯乙烯。3个水井的有机污染非致癌风险未超过限值1,在可接受的范围内,四氯化碳的非致癌风险所占比例最大,为89.85%; 3个采样点有机污染致癌风险,超出了其可接受水平的最小限制10-6,但均未超出可接受的致癌风险的最大限制10-4,风险指数均在10-6~5.0×10-5之间,应该引起关注,产生致癌风险的主要污染物为三氯乙烯。有机污染非致癌风险和致癌风险的主要暴露途径为呼吸吸入,其次是饮水吸收,皮肤接触暴露途径风险值最小。  相似文献   

Sensitive and rapid detection of two toxic microalgae Alexandrium by loop-mediated isothermal amplification     

ZHANG Fengying  SHI Yanhong  JIANG Keji  XU Zhaoli  MA Lingbo 《海洋学报(英文版)》2018,37(2):139-146

A loop-mediated isothermal amplification (LAMP) assay was designed and evaluated for rapid detection of the toxic microalgae Alexandrium catenella and A. minutum, which can produce paralytic shellfish poisoning (PSP). Two sets of four specific primers targeting these two species were derived from the sequence of internal transcribed spacer (ITS) of ribosomal DNA. The method worked well in less than an hour under isothermal conditions of 65℃. LAMP specificity was validated in closely related algae as a comparison, suggesting the strict specificity of the LAMP primers. Two visual inspection approaches were feasible to interpret the positive or negative results. The detection limits of A. catenella and A. minutum samples using the LAMP assay were found to be 5.6 and 4.5 pg DNA, respectively. The sensitivity of this LAMP assay was 10 or 100-fold higher than Polymerase Chain Reaction (PCR) method in detecting the two microalgae. These characteristics of species specificity, sensitivity, and rapidity suggest that this method has the potentiality in the monitoring of red tide caused by A. catenella and A. minutum.  相似文献